Véronique Gouverneur Research

Department of Chemistry University of Oxford


188 Hydrodifluoromethylation of Alkenes with Difluoroacetic Acid
Claudio F. Meyer, Sandrine M. Hell, Antonio Misale, Andrés A. Trabanco and
Véronique Gouverneur

Angew. Chem. Int. Ed. 2019, doi.org/10.1002/anie.201903801



187 The fluorination of C–H bonds: developments and perspectives
Robert Szpera, Daniel F. J. Moseley, Lewis B. Smith, Alistair J. Sterling and Véronique Gouverneur
Angew. Chem. Int. Ed. 2019, doi.org/10.1002/anie.201814457




186 Synthesis of 18F-Difluoromethylarenes Using Aryl Boronic Acids, Ethyl bromofluoroacetate and [18F]Fluoride
Jeroen B. I. Sap, Thomas C. Wilson, Choon Wee Kee, Natan J. W. Straathof,
Christopher W. amEnde, Paramita Mukherjee, Lei Zhang, Christophe Genicot and Véronique Gouverneur
Chem. Sci., 2019, 10, 3237 - 3241. DOI: 10.1039/C8SC05096A




185 Hydrogen Bonding Phase-Transfer Catalysis with Potassium Fluoride: Enantioselective Synthesis of β-Fluoroamines
Gabriele Pupo, Anna Chiara Vicini, David M. H. Ascough, Francesco Ibba,
Kirsten E. Christensen, Amber L. Thompson , John M. Brown , Robert S. Paton
and Veronique Gouverneur
J. Am. Chem. Soc. 2019, 141 (7), 2878–2883. DOI: 10.1021/jacs.8b12568




184 Synthesis and Reactivity of a-Cumyl Bromodifluoromethanesulfenate: Application to the Radiosynthesis of [18F]ArylSCF3
Jiang Wu, Qunchao Zhao, Thomas C. Wilson, Stefan Verhoog, Long Lu,
Véronique Gouverneur and Qilong Shen
Angew. Chem. Int. Ed. 2019, 58, 1 – 6. DOI: 10.1002/anie.20181370


183 Data-mining the diaryl(thio)urea conformational landscape: Understanding the contrasting behavior of ureas and thioureas with quantum chemistry
Guilian Luchini, David M.H. Ascough, Juan V. Alegre-Requena, Veronique Gouverneur, Robert S. Paton
Special Issue Paper: Computational Chemistry in Organic Synthesis. Guest Editors: Dean Tantillo and John Wood
Tetrahedron. 2019, 75(1), 697-702. DOI: 10.1016/j.tet.2018.12.033



182 Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides Stephen Hyde, Janis Veliks, David M.H. Ascough, Robert Szpera, Robert S. Paton,Véronique Gouverneur
Special Issue in honour of Prof Leon Ghosez
Tetrahedron. 2019, 75(1), 17-25. DOI: 10.1016/j.tet.2018.11.022


181 PET imaging of PARP expression using [18F]olaparib
Wilson TC, Xavier M-A, Knight J, Verhoog S, Torres JB, Mosley M, Hopkins SL, Wallington S, Allen PD, Kersemans V, Hueting R, Smart S, Gouverneur V, Cornelissen B
J Nuc Med. 2018, 60, 504-510. DOI: 10.2967/jnumed.118.213223





180 Boron reagents for divergent radiochemistry
Wilson TC, Cailly T and Gouverneur V
Chem Soc Rev. 2018, 47, 6990-7005







179 Asymmetric nucleophilic fluorination under hydrogen bonding phase-transfer catalysis
Pupo G, Ibba F, Ascough DMH, Vicini AC, Ricci P, Christensen KE, Pfeifer L, Morphy JR, Brown JM, Paton RS, Gouverneur V
Science. 2018, 360(6389), 638-642







178 Highly Diastereoselective Synthesis of Trifluoromethyl Indolines by Interceptive Benzylic Decarboxylative Cycloaddition of Nonvinyl, Trifluoromethyl Benzoxazinanones with Sulfur Ylides under Palladium Catalysis
N Punna, P Das, V Gouverneur, and N Shibata
Org Lett. 2018, 20(6), 1526-1529


177 Controlled Single and Double Iodofluorination of Alkynes with DIH- and HF-Based Reagents
L Pfeifer and V Gouverneur
Org Lett. 2018, 20(6), 1576-1579


176 Selective Radical Trifluoromethylation of Native Residues in Proteins
M Imiołek, G Karunanithy, W-L Ng, A Baldwin, V Gouverneur, and B Davis
J Am Chem Soc, 2018, 7 1568-1571





175 18F-Trifluoromethylation of Unmodified Peptides with 5-18F-(Trifluoromethyl)dibenzothiophenium Trifluoromethanesulfonate
S Verhoog, C Kee, Y Wang, T Khotavivattana, T Wilson, V Kersemans, S Smart, M Tredwell, B Davis and V Gouverneur
J Am Chem Soc, 2018, 7 1572-1575.








174 Synthesis, characterization, thermal and surface properties of co- and terpolymers based on fluorinated a-methylstyrenes and styrene
J. Walkowiak-Kulikowska,  A. Szwajca,  V. Gouverneur  and  B. Ameduri 
Polym Chem-Uk, 2017, 8, 6558-6569.





173 De-Risking the Cu-Mediated 18F-Fluorination of Heterocyclic PET Radioligands
Taylor, E. Emer, S. Preshlock, M. Schedler, M. Tredwell, S. Verhoog, J. Mercier, C. Genicot, and V. Gouverneur
J Am Chem Soc, 2017, 139, 8267-8276.






172 Synthesis and Reactivity of 18F-Labeled α,α-Difluoro-α-Aryloxyacetic Acids
T. Khotavivattana, S. Calderwood, S. Verhoog, L. Pfeifer, S. Preshlock, N. Vasdev, T. Collier, V. Gouverneur
Org. Lett. 2017, 19 (3), 568-571.






171 The Dual Role of Thiourea in the Thiotrifluoromethylation of Alkenes 
P. Ricci, T. Khotavivattana, L. Pfeifer, M. Médebielle, J. R. Morphy, V. Gouverneur 
Chem. Sci. 2017, 8, 1195-1199.




170 Bridging the gaps in 18F PET tracer development 
M. G. Campbell, J. Mercier, C. Genicot, V. Gouverneur, J. M. Hooker, T. Ritter 
Nat. Chem. 2017, 9, 1-3.








169 Twisting the Ethano-Tröger’s Base: The Bisamide 
J. Cvengros, R. Pereira, L. Pfeifer, J. Fournier, V. Gouverneur
Org. Biomol. Chem. 2017, 15, 628-633.